Chem 110 Lecture Notes, Fall 2003
These are the
notes I am using to present my lectures. They are here for the
convenience of my students. They are unedited and thus liable
to error. The expansions and corrections I put in during my lectures
are not included. Use them at your own risk!
You must have the font "Symbol" installed for your
browser to display all of the equations in some pages of notes.
If you find errors in my notes, please inform me ASAP via e-mail:
rap1 @ axe.humboldt.edu
Notes:
- Lecture 1_August 25: Introduction;
Review of Acid-Base Chemistry
- Lecture 2_August 27: pH; Acid-Base
Titration; Hydrolysis of Weak Salts.
- Lecture 3_August 29: Common
Ions, Buffers, and Buffer Preparation.
- Lecture 4_September 3: Aqueous
Ion Solubility, Ksp, Finding and Using Ksp
in solubility Problems; pH Effects.
- Lecture 5_September 5: pH Effects
of Ionic Solubility; Complex Ionic Equilibrium; Introduction
to Thermodynamics.
- Lecture 6_September 8: Thermodynamics,
Spontaneity, and Entropy.
- Lecture 7_September 10: Entropy
and Spontaneity; Free Energy; Free Energy and Chemical Processes.
- Lecture 8_September 12: Free
Energy and Chemical Reactions; More on Entropy.
- Lecture 9_September 15: Entropy
and Molecular Complexity; Free Energy Calculations.
- Lecture 10_September 17: Free
Energy Calculations cont.; Pressure Dependence of Free Energy;
Free Energy and Equilibria.
- Lecture 11_September 19: Free
Energy and Equilibria, cont.; Keq and Temperature;
Free Energy and Work.
- Lecture 12_September 22: Introduction
to Electrochemistry; Introduction to Galvanic Cells.
- Lecture 13_September 24: Galvanic
Cells; Electrodes and Standard Reduction Potentials; Cell Diagrams;
Cell Potential and Free Energy.
- Lecture 14_September 26: Calculating
Free Energy from Cell potentials; Concentration Cells; Potentiometry;
Reference Electrodes; The Glass Electrode.
- Lecture 15_September 29: Electrochemistry
cont. - Batteries; Electrolysis and Electrolytic Cells. (Guest
Lecture)
- Lecture 16_October 1: Electrochemical
Corrosion; Review of Classical Bonding. (Guest Lecture)
- Lecture 17_October 6: Bonding
Review - Lewis Structures, Resonance, and Expanded Valence Shells.
- Lecture 18_October 8: VSEPR
Theory and Molecular Geometry; Polarity and Polar Molecules.
- October 13: Exam I review - No Lecture Notes.
- Lecture 19_October 15: Introduction
to Quantum Models of Bonding.
- Lecture 20_October 17: Hybrid
Atomic Orbitals.
- Lecture 21_October 20: Molecular
Orbital Theory.
- Lecture 22_October 22: The Chemistry
of the Elements - Review of the Periodic Table and Chemical Periodicity.
- Lecture 23_October 24: Chemical
Demos - Period 3; Group 1 and 17.
- Lecture 24_October 27: The Chemistry
of the Representative Elements - Hydrogen; the Alkali Metals;
Introduction to the Alkaline Earth Metals.
- Lecture 25_October 29: The Chemistry
of the Representative Elements - the Alkaline Earth Metals.
- Lecture 26_October 31: The Chemistry
of the Representative Elements - Group III.
- Lecture 27_November 3: The Chemistry
of the Representative Elements - Group IV overview; Carbon, Silicon.
- Lecture 28_November 5: The Chemistry
of the Representative Elements - Group IV, cont.; Group V overview.
- Lecture 29_November 7: The Chemistry
of the Representative Elements - Group V, cont.
- Lecture 30_November 10: The
Chemistry of the Representative Elements - Group V, cont.; Group
VI.
- Lecture 31_November 12: The
Chemistry of the Representative Elements - Sulfur; Group VII.
- Lecture 32_November 17: The
Chemistry of the Representative Elements - Hydrogen Halides;
Introduction to the Transition Metals.
- Lecture 33_November 19: The
Chemistry of the Transition Metals; Coordination Compounds.
- Lecture 34_November 21: The
Chemistry of the Transition Metals; Naming Complex Ions, cont.;
Stereoisomerism.
- Lecture 35_December1: Stereoisomerism,
cont. Polydentate Ligands; Transition Metal Ion Colors; Hybrid
Orbital Theory and Transition Metal Ions.
- Lecture 36 December 3: Hybrid
Orbital Theory and Transition Metal Ions - Four Ligand Examples.
Crystal Field Theory - Paramagnetism and Colors.
- Lecture 37 December 5: Molecular
Orbital Theory for Transition Metal Complex Ions; Survey of Fourth
Period Transition Metals: Sc-Ti.
- Lecture 38 December 8: Survey
of Fourth Period Transition Metals: V-Zn; Other Transition Metals:
Ag & Au, Hg, Pt, Ir etc. W, Cd.
- Lecture 39 December 10: Nuclear
Chemistry - Review (Atoms and Isotopes); Radioactive Decay.
- Lecture 40 December 12: Nuclear
Chemistry - Radioactive Decay Series; Nuclear Decay Rates and
Dating.
© R A Paselk
Last modified 12 December 2003